李忠义

李忠义    博士、教授

地址：睢阳校区工科实训楼3楼305室

教育经历

2008.9-2013.7，大连理工大学，硕博连读，工学博士（导师：段春迎教授）

2003.9-2007.6，大连大学，理学学士

工作经历

2024.12-至今，永利23411集团化学化工学院，教授

2017.12-2024.12，永利23411集团化学化工学院，副教授

2013.7-2017.12，永利23411集团化学化工学院，讲师

主讲课程

中级无机化学，化工机械基础，无机化学实验，化工原理实验。

研究方向

金属有机功能配合物的组装及磁光性质。

科研项目

[1] 基于刚柔混合羧酸配体的三维Gd(III)分子基磁制冷剂的研制(编号25A150041），河南省高等学校重点科研项目，2025.01-2026.12，主持在研。

[2] 抗磁锌(II)调控的多维稀土荧光单分子磁体的可控合成及性能研究(编号222300420509），河南省自然科学基金面上项目，2022.01-2023.12，主持结项。

[3] 多维Gd(III)基分子基磁制冷剂的研制 （19A150005），河南省高等学校重点科研项目，2019.01-2020.12，主持结项。

[4] 稀土分子基磁制冷材料的研制 （172102210437），河南省重点研发与推广专项（科技攻关）项目，2017.01-2018.12，主持结项。

[5] 多维3d-Gd异金属分子基磁制冷剂的组装及磁性研究(21401126)，国家自然科学基金，2015.1-2017.12，主持结项。

代表性研究成果（2016年以来）

1. 论文

[1]  Zhong-Yi Li,* Xi-Meng Jia , Yi-Chen Wang , Le-Ran Zhang , Chi Zhang , Bin Zhai*. Magneto-structural correlations in two 2D Gd(III) coordination polymers exhibiting large magnetocaloric effect, J. Mol. Struct., 2026, 1353,144671.

[2]  Zhong-Yi Li,* Qiang Zhai , Wen-Yuan Zhao , Chi Zhang , Xiang-Fei Zhang , Bin Zhai*. Lanthanide metal-organic frameworks based on rigid-flexible dual ligands as ratiometric fluorescence sensor of tryptophan or as excellent magnetic refrigerant, J. Mol. Struct., 2025, 1339, 142433.

[3]  Zhongyi Li,* Jiahui Bu, Ran Zhang, Chi Zhang, Dongqing Wu, Bin Zhai*. Two temperature-dependent 2D heterometallic Cd(II)-Dy(III) coordination polymers exhibiting slow magnetic relaxation and luminescence properties, J. Rare Earths, 2023, 41, 613-620.

[4]  Zhong-Yi Li,* Han Chang, Jia-Jing Zhao, Chi Zhang, Dong-Qing Wu, Bin Zhai*. Tunable structures and magnetic / optical properties of six Cd(II)-based coordination polymers by introducing different para- or dia-magnetic metal ions, J. Mol. Struct., 2023, 1283, 135270

[5]  Zhong-Yi Li,* Peng-Yu Zhu , Han Chang, Zhen-Zhu Hou , Mei-Ling Shao, Bin Zhai *. Two novel 3D Zn(II)/Cd(II) MOFs with tri- or di-nuclear cluster units for multifunctional sensing applications in aqueous media, Dyes and Pigments, 2022, 207, 110719.

[6]  Zhong-Yi Li,* Ran Zhang, Peng-Yu Zhu, Chi Zhang, Dong-Qing Wu and Bin Zhai*. Structures and magnetic properties of two heterometallic Cu(II)–Cd(II) polymers exhibiting antiferromagnetic ordering, CrystEngComm, 2022, 24, 2410–2417

[7]  Zhong-Yi Li,* Xiao-Juan Li, Xuan Gao, Fu-Li Zhang, Chi Zhang, and Bin Zhai*. Dynamic Structural Transformation between 3D and 1D CdCo Heterometallic MOFs Showing Switchable Spin-Canted Antiferromagnetism, Cryst. Growth Des., 2020, 20, 1103−1109.

[8]  Zhong-Yi Li,* Wen-Jing Wang, Dong-Qing Wu, Chi Zhang, Fu-Li Zhang, Bin Zhai,* and Jian-Jun Zhang*. Two 1D carboxylate-bridged magnets displaying solvent-dependent canted antiferromagnetic ordering, CrystEngComm, 2019, 21, 4098–4103.

[9]  Zhong-Yi Li, Jian-Jun Zhang,* Shu-Qin Liu, Hui Zhang, Ying-Ji Sun, Xiao-Yu Liu, and Bin Zhai*. Heterometallic Hexanuclear [Ln₄Cr₂] Cluster-Based Three- Dimensional Sulfate Frameworks as a Magnetic Refrigerant and Single Molecular Magnet, Cryst. Growth Des., 2018, 18, 7335–7342.

[10]  Zhong-Yi Li, Ya-Lan Xu, Xiang-Fei Zhang, Bin Zhai*, Fu-Li Zhang, Jian-Jun Zhang*, Chi Zhang, Su-Zhi Li, and Guang-Xiu Cao*. Four one-dimensional lanthanide–phenylacetate polymers exhibiting luminescence and magnetic cooling/spin-glass behavior, Dalton Trans., 2017, 46, 16485–16492.

[11]  Zhong-Yi Li, Yan Chen, Xin-Ying Dong, Bin Zhai,* Xiang-Fei Zhang, Chi Zhang, Fu-Li Zhang, Su-Zhi Li, and Guang-Xiu Cao*. Two Types of Lanthanide Coordination Polymers Based on a Homophthalate Ligand Exhibiting Luminescence and a Significant Magnetocaloric Effect, Cryst. Growth Des., 2017, 17, 3877−3884.

[12]  Zhong-Yi Li, Yuan-Qing Cao, Jing-Yu Li, Xiang-Fei Zhang, Bin Zhai,* Chi Zhang, Fu-Li Zhang, and Guang-Xiu Cao*. Three Types of Lanthanide Coordination Polymers with Methylmalonate and Isonicotinate as Coligands: Structures, Luminescence, and Magnetic Properties. Cryst. Growth Des., 2017, 17, 6752−6761.

[13]  Zhong-Yi Li, Chi Zhang, Bin Zhai,* Jing-Cheng Han, Meng-Chun Pei, Jian-Jun Zhang,* Fu-Li Zhang, Su-Zhi Li, and Guang-Xiu Cao*. Linking heterometallic Cu–Ln chain units with a 2-methylenesuccinate bridge to form a 2D network exhibiting a large magnetocaloric effect. CrystEngComm, 2017, 19, 2702–2708.

[14]  Zhong-Yi Li,* Yuan-Qing Cao, Xiang-Ming Zhang, Ya-Lan Xu, Guang-Xiu Cao, Fu-Li Zhang, Su-Zhi Li, Fu-Qiang Zhang, and Bin Zhai*. Linking cobalt–water chains with cis-1,4-cyclohexanedicarboxylate bridges to form a 2D network exhibiting spin-canted antiferromagnetism. New J. Chem., 2017, 41, 457–461.

[15]  Zhong-Yi Li, Bin Zhai,* Su-Zhi Li, Guang-Xiu Cao, Fu-Qiang Zhang, Xiang-Fei Zhang, Fu-Li Zhang, and Chi Zhang. Two Series of Lanthanide Coordination Polymers with 2‑Methylenesuccinate: Magnetic Refrigerant, Slow Magnetic Relaxation, and Luminescence Properties. Cryst. Growth Des., 2016, 16, 4574−4581.

2. 专利

[1]  李忠义*，翟滨，张向飞，张弛，刘起峰，曹广秀，一种晶态钆基磁制冷材料及其制备方法，中国发明专利，专利号：ZL 201610540529.1，授权公告日：2019.2.12。

[2]  李忠义*，吴冬青，张向飞，翟滨，曹广秀，一种异金属[CdMn]荧光磁制冷材料及其制备方法，中国发明专利，专利号：ZL201910568391.X，授权公告日：2021.3.23。

[3]  李忠义*，赵兵，翟滨，吴冬青，邵梅玲，一种基于4,4’-联吡啶-衣康酸衍生配体的磁性钴(II)配合物及其制备方法，中国发明专利，专利号：ZL201810471811.8，授权公告日：2021.3.2。

[4]  李忠义*，张向飞，孙家书，翟滨，曹广秀，一种基于邻羧基苯乙酸配体的[CdNa₂]异金属荧光材料及其制备方法，中国发明专利，专利号：ZL201810568380.1，授权公告日：2021.6.11。

[5]  李忠义*，赵兵，翟滨，孙家书，张向飞，一种基于4,4’-联吡啶-衣康酸衍生配体的锌(II)荧光材料及其制备方法，中国发明专利，专利号：ZL201810471812.2，授权公告日：2021.5.04。